| Rank | Player | Country | Matches | 1st serve points won |
| 1 | P.Kohlschreiber | GER | 3 | 129 of 152 = 85 % |
| 2 | R.Gasquet | FRA | 4 | 169 of 203 = 83 % |
| 3 | F.Lopez | ESP | 2 | 78 of 97 = 80 % |
| 4 | R.Federer | SUI | 6 | 339 of 424 = 80 % |
| 5 | M.Raonic | CAN | 4 | 191 of 239 = 80 % |
| 6 | J.Del Potro | ARG | 3 | 159 of 199 = 80 % |
| 7 | N.Almagro | ESP | 5 | 228 of 286 = 80 % |
| 8 | S.Johnson | USA | 1 | 77 of 97 = 79 % |
| 9 | M.Cilic | CRO | 3 | 134 of 169 = 79 % |
| 10 | N.Djokovic | SRB | 7 | 359 of 456 = 79 % |
| 11 | J.Tsonga | FRA | 5 | 269 of 342 = 79 % |
| 12 | D.Brands | GER | 2 | 138 of 176 = 78 % |
| 13 | T.Robredo | ESP | 1 | 58 of 74 = 78 % |
| 14 | S.Querrey | USA | 3 | 144 of 185 = 78 % |
| 15 | J.Chardy | FRA | 5 | 291 of 374 = 78 % |
| 16 | L.Lacko | SVK | 2 | 125 of 161 = 78 % |
| 17 | E.Donskoy | RUS | 3 | 145 of 188 = 77 % |
| 18 | R.Williams | USA | 1 | 70 of 91 = 77 % |
| 19 | B.Tomic | AUS | 3 | 183 of 239 = 77 % |
| 20 | A.Murray | GBR | 7 | 340 of 445 = 76 % |