| Rank | Player | Country | Matches | 2nd serve points won |
| 1 | N.Djokovic | SRB | 7 | 157 of 239 = 66 % |
| 2 | M.Granollers | ESP | 2 | 35 of 54 = 65 % |
| 3 | D.Brands | GER | 2 | 51 of 79 = 65 % |
| 4 | C.Stebe | GER | 1 | 15 of 24 = 63 % |
| 5 | M.Raonic | CAN | 4 | 81 of 131 = 62 % |
| 6 | D.Istomin | UZB | 2 | 68 of 110 = 62 % |
| 7 | P.Kohlschreiber | GER | 3 | 64 of 106 = 60 % |
| 8 | M.Klizan | SVK | 1 | 22 of 37 = 59 % |
| 9 | R.Bautista Agut | ESP | 2 | 48 of 81 = 59 % |
| 10 | T.Robredo | ESP | 1 | 32 of 55 = 58 % |
| 11 | M.Llodra | FRA | 1 | 22 of 38 = 58 % |
| 12 | R.Berankis | LTU | 3 | 64 of 111 = 58 % |
| 13 | S.Stakhovsky | UKR | 1 | 19 of 33 = 58 % |
| 14 | N.Almagro | ESP | 5 | 144 of 251 = 57 % |
| 15 | T.Haas | GER | 1 | 46 of 81 = 57 % |
| 16 | S.Darcis | BEL | 1 | 21 of 37 = 57 % |
| 17 | N.Davydenko | RUS | 2 | 44 of 78 = 56 % |
| 18 | J.Melzer | AUT | 3 | 62 of 110 = 56 % |
| 19 | M.Youzhny | RUS | 2 | 78 of 139 = 56 % |
| 20 | L.Rosol | CZE | 2 | 49 of 88 = 56 % |